Preparation of Waterborne Epoxy Emulsion and Properties of MS-2 Micro-surfacing

LI Yue; ZHAO Chenyi; WU Yusheng; HUANG Zhou

doi:10.11936/bjutxb2022040010

Journal of Beijing University of Technology > 2023 > 49(8): 874-883. > DOI: 10.11936/bjutxb2022040010

LI Yue, ZHAO Chenyi, WU Yusheng, HUANG Zhou. Preparation of Waterborne Epoxy Emulsion and Properties of MS-2 Micro-surfacing[J]. Journal of Beijing University of Technology, 2023, 49(8): 874-883. DOI: 10.11936/bjutxb2022040010

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Preparation of Waterborne Epoxy Emulsion and Properties of MS-2 Micro-surfacing

LI Yue^1,,
ZHAO Chenyi^1, ,,
WU Yusheng^{2, 3},
HUANG Zhou^{2, 3}

1.
Key Laboratory of Urban Security and Disaster Engineering of Ministry of Education, Beijing University of Technology, Beijing 100124, China
2.
China Building Materials Test and Certification Group Xiamen Hongye Co., Ltd., Xiamen 361026, China
3.
Xiamen Key Laboratory of Performance Testing and Diagnosis of Building Engineering, Xiamen 361026, China

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Received Date: April 27, 2022
Revised Date: June 13, 2022
Available Online: June 12, 2023

Graphical Abstract

Abstract

Abstract

Using epoxy resin E51 and polyethylene glycol (PEG) as raw materials, waterborne epoxy emulsion was prepared by phase inversion method. By exploring the effects of PEG molecular weight and emulsifier dosage on the viscosity, particle size and stability of the emulsion, the waterborne epoxy emulsion with the best comprehensive performance was selected, and the thermal stability and micro-surfacing of the cured waterborne epoxy resin were analyzed. The compatibility between waterborne epoxy resin and emulsified asphalt was investigated by fluorescence microscope, and the optimum content of waterborne epoxy resin was obtained. On the basis of this, MS-2 waterborne epoxy resin modified emulsified asphalt micro-surfacing was prepared. The influences of different preparation methods and different curing agents on the construction performance and road performance of micro-surfacing mixture were investigated, and the cost performance of self-made emulsion and commercial emulsion and the corresponding micro-surfacing performance were analyzed. Results show that when the molecular weight of PEG is 6 000 and the content of emulsifier is 20%, the waterborne epoxy emulsion has the best comprehensive performance, and the corresponding waterborne epoxy cured product has excellent thermal stability and good micro-surfacing. 6% waterborne epoxy resin has the best compatibility with emulsified asphalt. The best preparation method of waterborne epoxy resin modified emulsified asphalt is to mix waterborne epoxy emulsion with emulsified asphalt and then add waterborne epoxy curing agent. Compared with the basic amine curing agent, the micro-surfacing prepared by waterborne epoxy curing agent has excellent comprehensive properties. Self-made waterborne epoxy emulsion has higher cost performance than that of commercial emulsion, and has good application value.

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References (21)

References

[1]	王玉杰. 水性环氧树脂改性乳化沥青的应用研究综述[J]. 江西建材, 2016(16): 181-184. https://www.cnki.com.cn/Article/CJFDTOTAL-JXJC201616155.htm WANG Y J. Review on application research of waterborne epoxy resin modified emulsified asphalt[J]. Jiangxi Building Materials, 2016(16): 181-184. (in Chinese) https://www.cnki.com.cn/Article/CJFDTOTAL-JXJC201616155.htm
[2]	张小兵. 微表处技术在公路预防性养护中的应用[J]. 中国高新科技, 2021(8): 43-44, 70. https://www.cnki.com.cn/Article/CJFDTOTAL-GXKE202108018.htm ZHANG X B. Application of micro surfacing technology in highway preventive maintenance[J]. China High Tech, 2021(8): 43-44, 70. (in Chinese) https://www.cnki.com.cn/Article/CJFDTOTAL-GXKE202108018.htm
[3]	何俊明. 微表处技术在公路预防性养护中的应用[J]. 江西建材, 2016(19): 138-137. https://www.cnki.com.cn/Article/CJFDTOTAL-JXJC201619115.htm HE J M. Application of micro surfacing technology in highway preventive maintenance[J]. Jiangxi Building Materials, 2016(19): 138-137. (in Chinese) https://www.cnki.com.cn/Article/CJFDTOTAL-JXJC201619115.htm
[4]	张庆, 郝培文, 白正宇. 水性环氧树脂改性乳化沥青混凝土性能研究[J]. 筑路机械与施工机械化, 2016, 33(1): 54-57. https://www.cnki.com.cn/Article/CJFDTOTAL-ZLJX201601023.htm ZHANG Q, HAO P W, BAI Z Y. Study on performance of waterborne epoxy resin modified emulsified asphalt concrete[J]. Road Construction Machinery and Construction Mechanization, 2016, 33(1): 54-57. (in Chinese) https://www.cnki.com.cn/Article/CJFDTOTAL-ZLJX201601023.htm
[5]	刘宁, 钟海燕, 杨志鹏, 等. 水性环氧树脂改性乳化沥青混凝土性能研究[J]. 现代交通技术, 2017, 14(4): 1-4. https://www.cnki.com.cn/Article/CJFDTOTAL-JTJZ201704001.htm LIU N, ZHONG H Y, YANG Z P, et al. Study on performance of waterborne epoxy resin modified emulsified asphalt concrete[J]. Modern Transportation Technology, 2017, 14(4): 1-4. (in Chinese) https://www.cnki.com.cn/Article/CJFDTOTAL-JTJZ201704001.htm
[6]	GU J W, YANG X T, LI C M, et al. Synthesis of cyanate ester microcapsules via solvent evaporation technique and its application in epoxy resins as a healing agent[J]. Industrial & Engineering Chemistry Research, 2016, 55(41): 10914-10946.
[7]	CREYTENS K, GILISSEN L, HUYGENS S, et al. A new application for epoxy resins resulting in occupational allergic contact dermatitis: the three-dimensional printing industry[J]. Contact Dermatitis, 2017, 77(5): 349-351.
[8]	何丽红, 杨帆, 谷雨, 等. 非离子型水性环氧树脂乳化剂的制备及其乳液性能的研究[J]. 电镀与涂饰, 2017(14): 32-36. https://www.cnki.com.cn/Article/CJFDTOTAL-DDTL201714010.htm HE L H, YANG F, GU Y, et al. Preparation of nonionic waterborne epoxy resin emulsifier and study on its emulsion performance[J]. Electroplating and Finishing, 2017(14): 32-36. (in Chinese) https://www.cnki.com.cn/Article/CJFDTOTAL-DDTL201714010.htm
[9]	金永香, 连海兰. 环氧树脂的相反转乳化技术研究进展[J]. 涂料工业, 2018, 48(9): 70-76. https://www.cnki.com.cn/Article/CJFDTOTAL-TLGY201809013.htm JIN Y X, LIAN H L. Research progress of phase inversion emulsification technology of epoxy resin[J]. Coating Industry, 2018, 48(9): 70-76. (in Chinese) https://www.cnki.com.cn/Article/CJFDTOTAL-TLGY201809013.htm
[10]	杨红光, 杨建军, 吴庆云, 等. 非离子型水性环氧-聚氨酯乳液的制备及性能研究[J]. 涂料工业, 2016, 46(8): 53-57. https://www.cnki.com.cn/Article/CJFDTOTAL-TLGY201608011.htm YANG H G, YANG J J, WU Q Y, et al. Preparation and performance study of nonionic waterborne epoxy-polyurethane emulsion[J]. Coating Industry, 2016, 46(8): 53-57. (in Chinese) https://www.cnki.com.cn/Article/CJFDTOTAL-TLGY201608011.htm
[11]	龙杰, 黄雪立, 闫锦. 基于相反转法合成的水性环氧树脂性能研究[J]. 塑料科技, 2020, 48(12): 58-62. https://www.cnki.com.cn/Article/CJFDTOTAL-SLKJ202012014.htm LONG J, HUANG X L, YAN J. Study on properties of waterborne epoxy resin synthesized by phase inversion method[J]. Plastic Science and Technology, 2020, 48(12): 58-62. (in Chinese) https://www.cnki.com.cn/Article/CJFDTOTAL-SLKJ202012014.htm
[12]	贺绍辉, 闫福安, 张志丰. 水性环氧乳液乳化剂合成及其乳液制备[J]. 中国涂料, 2021, 36(2): 25-31. https://www.cnki.com.cn/Article/CJFDTOTAL-ZGTU202102006.htm HE S H, YAN F A, ZHANG Z F. Synthesis of waterborne epoxy emulsion emulsifier and its emulsion preparation[J]. China Coatings, 2021, 36(2): 25-31. (in Chinese) https://www.cnki.com.cn/Article/CJFDTOTAL-ZGTU202102006.htm
[13]	ZHANG Q, XU Y H, WEN Z G. Influence of water-borne epoxy resin content on performance of waterborne epoxy resin compound SBR modified emulsified asphalt for tack coat[J]. Construction and Building Materials, 2017, 153: 774-782.
[14]	王佳炜. 水性环氧—乳化沥青结构形成及性能影响因素研究[D]. 重庆: 重庆交通大学, 2015: 24-28. WANG J W. Study on structure formation and performance influencing factors of waterborne epoxy emulsified asphalt[D]. Chongqing: Chongqing Jiaotong University, 2015: 24-28. (in Chinese)
[15]	周启伟, 凌天清, 郝增恒, 等. 水性环氧树脂-乳化沥青共混物特性分析[J]. 建筑材料学报, 2018, 21(3): 414-419. https://www.cnki.com.cn/Article/CJFDTOTAL-JZCX201803012.htm ZHOU Q W, LING T Q, HAO Z H, et al. Characteristic analysis of waterborne epoxy resin emulsified asphalt blends[J]. Journal of Building Materials, 2018, 21(3): 414-419. (in Chinese) https://www.cnki.com.cn/Article/CJFDTOTAL-JZCX201803012.htm
[16]	李秀君, 惠致富, 严慧忠, 等. 水性环氧树脂改性乳化沥青黏结性能试验分析[J]. 建筑材料学报, 2019, 22(1): 160-166. https://www.cnki.com.cn/Article/CJFDTOTAL-JZCX201901025.htm LI X J, HUI Z F, YAN H Z, et al. Experimental analysis of adhesive performance of emulsified asphalt modified by waterborne epoxy resin[J]. Journal of Building Materials, 2019, 22(1): 160-166. (in Chinese) https://www.cnki.com.cn/Article/CJFDTOTAL-JZCX201901025.htm
[17]	陈舟宇, 刘鲁清, 闫兆柏. 水性环氧改性乳化沥青微表处制备及性能研究[J]. 筑路机械与施工机械化, 2020, 37(5): 7-10, 14. https://www.cnki.com.cn/Article/CJFDTOTAL-ZLJX202006001.htm CHEN Z Y, LIU L Q, YAN Z B. Micro-surfacing preparation and performance study of waterborne epoxy modified emulsified asphalt[J]. Road Construction Machinery and Construction Mechanization, 2020, 37(5): 7-10, 14. (in Chinese) https://www.cnki.com.cn/Article/CJFDTOTAL-ZLJX202006001.htm
[18]	郭寒, 韩森, 王兆宇. 水性环氧微表处路用性能研究[J]. 内蒙古公路与运输, 2019(2): 51-55. https://www.cnki.com.cn/Article/CJFDTOTAL-NMGY201902013.htm GUO H, HAN S, WANG Z Y. Study on road performance of waterborne epoxy micro-surfacing[J]. Inner Mongolia Highway and Transportation, 2019(2): 51-55. (in Chinese) https://www.cnki.com.cn/Article/CJFDTOTAL-NMGY201902013.htm
[19]	LIU M M, HAN S, WANG Z Y, et, al. Performance evaluation of new waterborne epoxy resin modified emulsified asphalt micro-surfacing[J/OL]. Construction and Building Materials, 2019, 214: 93-100[2023-06-19]. https://www.sciencedirect.com/science/article/pii/S0950061819309894?via%3Dihub.
[20]	季节, 刘禄厚, 索智, 等. 水性环氧树脂改性乳化沥青微表处性能[J]. 长安大学学报(自然科学版), 2017, 37(5): 23-30. https://www.cnki.com.cn/Article/CJFDTOTAL-XAGL201705004.htm JI J, LIU L H, SUO Z, et al. Micro surface treatment performance of waterborne epoxy resin modified emulsified asphalt[J]. Journal of Chang'an University (Natural Science Edition), 2017, 37(5): 23-30. (in Chinese) https://www.cnki.com.cn/Article/CJFDTOTAL-XAGL201705004.htm
[21]	郑木莲, 范贤鹏, 刘富强, 等. 复配型水性环氧乳化沥青微表处耐久性[J]. 长安大学学报(自然科学版), 2020, 40(1): 68-76. https://www.cnki.com.cn/Article/CJFDTOTAL-XAGL202001007.htm ZHENG M L, FAN X P, LIU F Q, et al. Micro-surfacing durability of compound waterborne epoxy emulsified asphalt[J]. Journal of Chang'an University (Natural Science Edition), 2020, 40(1): 68-76. (in Chinese) https://www.cnki.com.cn/Article/CJFDTOTAL-XAGL202001007.htm

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Preparation of Waterborne Epoxy Emulsion and Properties of MS-2 Micro-surfacing