Structure Characterization and Luminescent Properties of Mesoporous SiO<sub>2</sub> Loaded With 1,8-Naphthalic Anhydride

SUN Ji-hong; LI Yu-zhen; WU Xia; GAO Lin

doi:10.3969/j.issn.0254-0037.2013.10.023

Journal of Beijing University of Technology > 2013 > 39(10): 1570-1575. > DOI: 10.3969/j.issn.0254-0037.2013.10.023

SUN Ji-hong, LI Yu-zhen, WU Xia, GAO Lin. Structure Characterization and Luminescent Properties of Mesoporous SiO₂ Loaded With 1,8-Naphthalic Anhydride[J]. Journal of Beijing University of Technology, 2013, 39(10): 1570-1575. DOI: 10.3969/j.issn.0254-0037.2013.10.023

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Structure Characterization and Luminescent Properties of Mesoporous SiO₂ Loaded With 1,8-Naphthalic Anhydride

College of Environmental and Energy Engineering, Beijing University of Technology, Beijing， 100124， China

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Received Date: May 08, 2011
Available Online: November 02, 2022

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Abstract

The organic-inorganic luminescent hybrid mesoporous materials (LHMS) was prepared via aminopropyl groups modification and subsequently 1, 8-Naphthalic anhydride loading by using bimodal mesoporous materials (BMMs) and MCM-41 as carriers, respectively.The resultant hybrid materials were characterized by XRD, TEM, SEM, BET, FT-IR and PL methods.It was showed that the emission peak position of LHMS-BMMs is around 444 nm, while for LHMS-MCM-41 with about 450 nm, demonstrating that the blue-shift phenomenon of LHMS-BMMs was more remarkable than that of LHMS-MCM-41.The most reason is the different morphology and related particle sizes between BMMs and MCM-41: BMMs is of spherical particle with a size of around 50 nm and uniform mesopores (about 3 nm) , while MCM-41 reveals irregular particle distribution in the range of 1-3 μm, but with uniform one-dimensional mesopores (about 3 nm) .
- bimodal mesoporous materials,
- 1, 8-Naphthalic anhydride,
- immobilization,
- fluorescent signaling

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Structure Characterization and Luminescent Properties of Mesoporous SiO2 Loaded With 1,8-Naphthalic Anhydride

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Structure Characterization and Luminescent Properties of Mesoporous SiO₂ Loaded With 1,8-Naphthalic Anhydride