Citation: | WANG Xiangke, WANG Dong, GAO Hong, YANG Huai. SRA-SA Transition in NLO Properties of Symmetry Porphyrin Derivatives Derived From Click Chemistry[J]. Journal of Beijing University of Technology, 2016, 42(12): 1916-1920. DOI: 10.11936/bjutxb2016050045 |
To improve the nonlinear optical (NLO) properties of materials, the porphyrins were modified by post-functionalizations using typical [2+2] click reactions. Their NLO properties were studied by Z scan technology. The effect of the different conjugated-systems and electron-withdrawing properties on NLO properties of the novel porphyrins was discussed based on the different chemical structures (kinds of the central ions and the click moieties). One special NLO phenomena was observed here. As the side groups, the click moieties strongly affected the third-order NLO responses, and all the compounds exhibited the RSA-SA reversed NLO properties.
[1] |
KANIS DR,RATNER MA,MARKS TJ.Design synthesis and properties of molecule based assemblies with large second order optical nonlinearities[J].Chemical Reviews,1994,34(2):155-173.
|
[2] |
MAH,JEN AK,DALTON LR.Polymer based optical waveguide materials processing and devices[J].Advanced Materials,2002,14(14):1339-1365.
|
[3] |
KULYKB,KERASIDOU AP,SOUMAHOROL,et al.Optimization and diagnostic of nonlinear optical features of pi-conjugated benzodifuran-based derivatives[J].RSC Advances,2016,6(18):14439-14447.
|
[4] |
HET,ZHANGB,WANG GC,et al.High efficiency THz-wave modulators based on conjugated polymer-based organic films[J].Journal of Physics D-Applied Physics,2016,49(7):1-8.
|
[5] |
CHEMLA DS,ZYSSJ.Nonlinear optical properties of organic molecules and crystals[M].Cambridge:Academic Press,1987:13-600.
|
[6] |
CHNITIM,CASSAGNEC, GODET J L, et al. Investigation of the third-order nonlinear optical properties in porphyrin solutions in the picosecond regime[J].Journal of Nonlinear Optical Physics& Materials,2015,24(3):1550030.
|
[7] |
AL-OMARIS.Kinetic model for the molecular system of Zinc(Ⅱ)-2, 9, 16, 23-phthalocyaninetetracarboxylate[J].Journal of Nonlinear Optical Physics & Materials,2015,24(1):1550005.
|
[8] |
CHENCH,YANG ZN,QIU FX,et al.Novel three chiral azobenzene polyurethanes: preparation, optical properties and simulation comparisons of two different polymeric thermo-optic switches[J].Journal of Nonlinear Optical Physics & Materials,2015,24(3):1550028.
|
[9] |
HAMBIR SA,WOLFED,BLANCHARD GJ,et al.Adjusting the third-order nonlinear optical properties of a conjugated polymer film[J].Journal of The American Chemical Society,1997,119(31):7367-7373.
|
[10] |
ORTIZA,INSUASTYB,TORRES MR,et al.Aminopyrimidine-based donor-acceptor chromophores: push-pull versus aromatic behavior[J].European Journal of Organic Chemistry,2008,2008(1):99-108.
|
[11] |
LIANG PX,DU ZC,WANGD,et al.Optoelectronic and self-assembly properties of porphyrin derivatives with click chemistry modification[J].Chem Phys Chem,2014,15(16):3523-3529.
|
[12] |
ZHANG WS,WANGD,CAOH,et al.Energy level tunable pre-click functionalization of fullerene for nonlinear optics[J].Tetrahedron,2014,70(3):573-577.
|
[13] |
JIN ZK,WANGD,WANG XK,et al.Efficient modification of pyrene-derivative featuring third-ordernonlinear optics via the click post-functionalization[J].Tetrahedron Letters,2013,54(36):4859-4864.
|
[14] |
MI YS,LIANG PX,JIN ZK,et al.Synthesis and third-order nonlinear optical properties of triphenylene derivatives modified by click chemistry[J].Chem Phys Chem,2013,14(18):4102-4108.
|
[15] |
LIANG PX,LI ZQ,MI YS,et al.Pyrene-based small molecular nonlinear optical materials modified by “click-reaction”[J].Journal of Electronic Materials,2015,44(8):2883-2889.
|
[16] |
JIANGL,LU FS,CHANGQ,et al.Fabrication of ultrathin films with large third-order nonlinear optical properties[J].Chem Phys Chem,2005,6(3):481-486.
|
[17] |
HUGHESS,SPRUCEG,WHERRETT BS,et al.The saturation limit to picosecond, induced absorption in dyes[J].Journal of Optical Communications and Networking,1993,100(100):113-117.
|
[18] |
GAO YC,ZHANG XR,LI YL,et al.Saturable absorption and reverse saturable absorption in platinum nanoparticles[J].Journal of Optical Communications and Networking,2005,251(251):429-433.
|
[19] |
ZHENG XQ,FENGM,LI ZG,et al.Enhanced nonlinear optical cesproperties of nonzero-bandgap graphene materials in glass matri[J].Journal of Materials Chemistry C,2014,2(21):4121-4125.
|
[20] |
FACCINETTOA,MAZZUCATOS,PEDROND,et al.Non-resonant z-scan characterization of the third-order nonlinear optical properties of conjugated poly (thiopheneazines)[J].Chem Phys Chem,2008,9(14):2028-2034.
|
[21] |
VAROTTOA,NAM CY,RADIVOJEVICI,et al.Phthalocyanine blends improve bulk heterojunction solar cells[J].Journal of the American Chemical Society,2010,132(8):2552-2554.
|
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