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WANG Xiangke, WANG Dong, GAO Hong, YANG Huai. SRA-SA Transition in NLO Properties of Symmetry Porphyrin Derivatives Derived From Click Chemistry[J]. Journal of Beijing University of Technology, 2016, 42(12): 1916-1920. DOI: 10.11936/bjutxb2016050045
Citation: WANG Xiangke, WANG Dong, GAO Hong, YANG Huai. SRA-SA Transition in NLO Properties of Symmetry Porphyrin Derivatives Derived From Click Chemistry[J]. Journal of Beijing University of Technology, 2016, 42(12): 1916-1920. DOI: 10.11936/bjutxb2016050045
shu

SRA-SA Transition in NLO Properties of Symmetry Porphyrin Derivatives Derived From Click Chemistry

  • 1.

    Department of Materials Physics and Chemistry, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China

  • 2.

    China Academy of Space Technology, Beijing 100094, China

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  • Received Date: May 16, 2016
  • Available Online: May 28, 2023
    Graphical Abstract
    • Abstract

  • To improve the nonlinear optical (NLO) properties of materials, the porphyrins were modified by post-functionalizations using typical [2+2] click reactions. Their NLO properties were studied by Z scan technology. The effect of the different conjugated-systems and electron-withdrawing properties on NLO properties of the novel porphyrins was discussed based on the different chemical structures (kinds of the central ions and the click moieties). One special NLO phenomena was observed here. As the side groups, the click moieties strongly affected the third-order NLO responses, and all the compounds exhibited the RSA-SA reversed NLO properties.

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