Capturing Pb2+ and Its Stability of CSH With Coexistence Multiple Heavy Metals Irons
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Graphical Abstract
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Abstract
By using solution synthesized method,the ability and long-term stability of CSH gel with different calcium silicon ratio to capture Pb2+ions at the liquid phase hydration with multiple heavy metal ions coexistence were studied by X-ray diffraction analysis,scanning electron microscopy analysis and other analysis method. The research showed that there were big difference at the ability of CSH capture Pb2+between a single ion and multiple heavy metal ions coexist,and the mechanisms and capture Pb2+ability of CSH gel with different calcium silicon ratios were different. When Pb2+content were low at the hydration solution,the ability of CSH gel capture Pb2+were high. While Pb2+content were high at the hydration solution,the capture capability to Pb2 +of CSH( Ⅰ) was significantly reduced,and CSH( Ⅱ)was still high,and the capture capability had been enhanced with multiple heavy metal ions coexistence.With prolonged hydration age( about 210 days),the capture capability of CSH gel to Pb2+changed.Freeze-thaw cycles have a greater impact on the CSH( Ⅰ) capture capability to Pb2+. In the freeze-thawcycles and chloride complexes under the action of erosion,the capabilities of C-S-H gel capturing Pb2+were significantly reduced.
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