Disinfectant Efficacy of Chlorine and Chlorine Dioxide in Nitrification Control in Water Distribution Systems
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摘要: 采用2台串联BAR模拟给水管网系统, 通过对余氯、NH4+-N、NO2--N、NO3--N、DO、HPC及AOB等指标检测, 评价氯和二氧化氯2种消毒剂对氯胺消毒管网中硝化作用的控制效果.研究结果表明:二氧化氯比等量氯更易提高管网中余氯质量浓度和DO质量浓度;氯消毒阶段NH4+-N降解, NO2--N和NO3--N积累, 而投加二氧化氯后可有效控制硝化作用;与投加氯消毒相比, 投加等质量浓度 (0.6 mg/L) 二氧化氯时, 第1台BAR中悬浮和生物膜中HPC分别降低了2.54 log和1.63 log, 悬浮及生物膜中AOB降低约1 log;二氧化氯能对AOB起到控制灭活效果而等量氯对其几乎没有灭活效果, 在控制供水管网硝化作用方面, 二氧化氯与氯胺联用的消毒效果优于氯与氯胺.Abstract: Two biofilm annular reactors (BAR) in series were adopted in the study, and the effects of chlorine and chlorine dioxide disinfection on nitrification were compared by analyzing residue chlorine, NH4+-N, NO2--N, NO3--N, DO, HPC and AOB.The results showed that chlorine dioxide was more effective than chlorine in enhancing the effluent concentration of residue chlorine and DO.The concentration of NH4+-N was droped while NO2--N and NO3--N were increased during the stage of chlorine, but not happening during the stage of chlorine dioxide.Compared with equivalent chorine (0.6mg/L) , the chlorine dioxide was more effective in removing suspended and boifilm HPC with 2.54 log and 1.63 log reductions, respectively, and both suspended and biofilm AOB with 1 log reduction.Chlorine was ineffective in controlling AOB.Therefore, the effect of chorine dioxide combined with chloramine was better than chorine combined with chloramine in mitigating nitrification in distribution systems.
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Keywords:
- disinfection /
- chloramine /
- chlorine dioxide /
- AOB /
- HPC /
- nitrification /
- water distribution systems
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