聚合物胶体的化学-力学相互作用

    Research on Chemo-mechanical Interaction of Polymer Gel

    • 摘要: 基于热力学框架的混合理论描述了聚合物胶体材料化学-力学行为的相互作用,建立了包含聚合物胶体化学-力学相互作用的两相模型,推导了聚合物胶体化学-力学相互作用的有限元方程.通过有限元算例分析了聚合物胶体板在受到化学载荷作用时的变形和受到均布力学载荷作用时的浓度变化.结果表明本文提出的化学-力学的相互作用的理论和方法能模拟聚合物胶体的化学-力学耦合行为.

       

      Abstract: The polymer gel can be described within the mixture theory based on the framework of thermodynamics.A biphasic model is proposed for the phenomenological description of chemo-mechanical interaction of the polymer gel.The finite element equations of the chemo-mechanical behavior have been derived in this paper.Two numerical examples,which include chemical loadings or mechanical loading imposed on the polymer,are simulated using the present finite element method.The results testify that the model in this paper can describe the chemo-mechanical coupling behavior of polymer gel.

       

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