Abstract:
Effects of the constitutes of sludge dewatering filtrate on phosphorus recovery in form of struvite (MgNH
4PO
4·6H
2O) were studied by using batch stirring reactors.The results showed that with keeping stirring speed at 200 rpm,stirring time at 180 min and precipitation time at 60 min in all experiments,pH of sludge dewatering filtrate rose after stirring without reagent addition;however,it was not enough to form struvite.When the concentration of PO
43- was at 4.00 mmol/L,more than 90% of the PO
43- was recovered. But only the initial concentration of Mg
2+ in sludge dewatering filtrate exceeded above 5.00 mmol/L,the reaction between Ca
2+ and PO
43- was inhibited distinctly and the ratio of the recovery molar concentration of PO
43-、Mg
2+ and NH
4+ could nearly reach 1:1:1.which means that the most quantity struvite were formed. When pH ranged from 10.0 to 10.5,the most quantity of struvite formed.Turbidity of sludge dewatering filtrate had negative effect on the recovery of Mg
2+ and struvite formation.