CSTR中三变量连续放热化学反应模型的非线性分析

    The Non-linear Analysis of the Chemical Reaction Models of Three-variable Consecutive Exothermal Reactions in CSTR

    • 摘要: 研究了修正的CSTR中具有两步连续放热反应的三变量化学模型的非线性动力学现象.建立了CSTR中具有两步连续放热反应的三变量化学模型的量纲一的数学模型.并进行了数值模拟分析.结果表明,本文所研究的化学模型,通过改变对热反馈的控制,可以得到丰富的非线性化学动力学现象,牛顿冷却时间τN和量纲一的活化能量ε对反应的进行具有一定的控制作用.当其它的参数和ε值确定时,在一定的范围内变化τN的值,可以使化学反应产生振荡和混沌现象.

       

      Abstract: This paper is concerned with the non-linear kinetic phenomenon of the three-variable chemical models with two consecutive exothermal reactions in CSTR. The non-dimensional mathematic model of the chemical model is established and analyzed qualitatively by numerical simulation. It is seen from the results of the numerical simulation that the rich non-linear kinetic phemomenon can be obtained by changing thermal feedback, and the reactions are controlled by the change of the Newton cooling time τN and non-dimensional active energy ε. Chemical oscillations and chemical chaos can be obtained by changing τN in a certain sphere under the condition that the ε and other parameters are determined.

       

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