硝酸盐氮对反硝化除磷的影响及过程控制

    Effects of Nitrate on Denitrifying Phosphorus Removing and the Process Control

    • 摘要: 针对南方地区低碳城市污水的特点,探讨了ρ(NO3- -N)及其投加方式对DPB反硝化除磷的影响,并利用在线监测技术提出相应的优化控制策略.结果表明,ρ(NO3- -N)过高或过低,均会降低DPB的反硝化除磷效率,为保证DPB的高效除磷效果,应投加适宜的ρ(NO3- -N);通过对V(ORP)与pH的在线监测发现,在反硝化除磷过程中,硝酸盐不足量时,pH在硝酸盐消耗完毕、缺氧吸磷结束时出现折点;NO3- -N足量时,pH在缺氧吸磷结束时出现平台区,pH可以指示反硝化吸磷情况,对工艺的运行工况进行优化控制.而V(ORP)未出现指示反硝化和缺氧吸磷结束的特征点,无法作为反硝化吸磷过程的控制参数;NO3- -N的投加方式不影响反硝化除磷效率,但随投加次数增加,尤其是连续低浓度投加的方式,更有利于提高脱氮效果,降低系统内NO2- -N的积累量.

       

      Abstract: Based on the characteristics of low carbon source of municipal wastewater in the southern regions, this paper studied the effects of different concentration and addition mode of nitrate on denitrifying phosphorus removal with nitrate as electron acceptor,and it was specially studied that the control strategy with on-line monitoring V(ORP)and pH.The experiments showed that the higher or lower concentration of nitrate in anoxic phase can lower simultaneous phosphorus and nitrogen removal.In order to achieve good and stable simultaneous phosphorus and nitrogen removal over time,the concentration of nitrate should be in a proper range.With on-line monitoring V(ORP)and pH,there would be a turning point in pH when nitrate was used up and phosphorus uptake ended,if nitrate wasn't enough.When phosphorus uptake ended with nitrate enough,there was a plat in pH.So pH can reflect the condition of phosphorus uptake and denitrifying in anoxic phase and can be used to optimize and control denitrifying phosphorus removal processes.While there wasn't any characteristic point in V(ORP)to infer the condition of phosphorus uptake and denitrifying in anoxic phase,V(ORP)can't be the controlling parameter in denitrifying phosphorus removal processes.The addition mode of nitrate couldn't affect the efficiency of simultaneous phosphorus and nitrogen removal,but it was favorable to advance denitrification rate and decrease accumulation of nitrite along with addition number of frequency increasing and continuous addition with low concentration nitrate especially.

       

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