复合絮凝剂CBF-737处理富营养化景观水体及其絮凝机理

    Treatment of Eutrophic Landscape Water by Compound Flocculant CBF-737 and Its Flocculating Mechanism

    • 摘要: 研究了复合型絮凝剂CBF-737(聚合氯化铝和生物絮凝剂MBF-737复配使用)处理富营养化景观水体的效果.结果表明:对于100 mL富营养化高藻水体, 加入1.8 mL的复合絮凝剂CBF-737(0.9 mL 5 g/L PAC和0.9 mL 2.5 g/L MBF-737), 1.5 mL的1%CaCl2作助凝剂, 280 r/min快速搅拌60 s, 100 r/min慢速搅拌45 s, 混凝效果最好.水体的浊度、总磷和残铝分别由58.3 NTU、1.94 mg/L和0.383 mg/L降低到2.98 NTU、0.198 mg/L和0.178 mg/L, 此时对藻类的去除率几乎接近于100%.复合絮凝剂CBF-737处理富营养化水体的混凝机理为生物絮凝剂MBF-737中大量的—OH、—COOH等基团与水中胶体以离子键结合;而PAC在水体中迅速水解, 压缩双电层, 破坏胶体稳定性;同时助凝剂CaCl2类似于成核物质, 通过生物絮凝剂吸附架桥和网捕作用形成密实的絮体.

       

      Abstract: The compound flocculant CBF-737 (the compound of polyaluminum chloride (PAC) and biological MBF-737) was used to treat eutrophic landscape water in this study.Results showed that adding 1.8 mL compound flocculant CBF-737 (0.9 mL of 5 g/L PAC and 0.9 mL of 2.5 g/L MBF-737) , and 1.5 mL of 1% CaCl2 to 100 mL eutrophic water, the optimal hydraulic conditions were as follows: quickly mixing speed of 280 r/min for 60 s, slowly mixing speed of 100 r/min for 45 s. The water turbidity, total phosphorus and residual aluminum were reduced from 58. 3 NTU, 1.94 mg/L and 0.383 mg/L to 2.98 NTU, 0.198 mg/L and 0.178 mg/L, respectively. Moreover, the removal ratio of algae almost reached 100%. Composite flocculant CBF-737 treatment of the eutrophic water coagulation mechanism was as follows: aqueous colloidal was combined with the —OH, —COOH group of MBF-737 by electrovalent bond; the PAC was rapidly hydrolyzed in the water, which could compress electric double layer and destroy the colloidal stability; and CaCl2 as the nucleation material, solid flocs formed through the biological flocculation agent adsorption bridge and enmeshment action.

       

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