用紫外光谱参数表征污水中溶解性有机污染物

    Ultraviolet Absorption Spectrum Characterization Approach for Quantitative Analysis of Dissolved Organic Contaminants in Sewage

    • 摘要: 为实现污水水质的实时在线监测,采用紫外吸收光谱法测定了洗浴废水和生活污水生物处理前后的紫外吸光特性,给出了定量表征污水中溶解性有机污染物的紫外光谱参数,并与常规有机污染物水质指标化学需氧量、总有机碳相关联.结果表明,波长为254 nm的紫外吸光度和波长在226~400 nm范围内的紫外吸光度的积分与化学需氧量、总有机碳均具有很好的线性关系.其中,紫外吸光度积分与总有机碳的相关性最高,能更加全面地反映污水中有机污染物的含量,测定迅速简便,无需消耗化学药剂,在一定程度上可替代常规有机污染物指标,是一种绿色水质分析方法.

       

      Abstract: The authors had studied ultraviolet absorption spectrum character of organic contaminants in sewage samples collected from bathing wastewater,domestic wastewater,along with their effluents of bio-treating installation.The authors put forward that ultraviolet absorption spectrum parameter of a dissolved organic contaminants in sewage correlates with the traditional comprehensive index of organic contaminant,such as Chemical Oxygen Demand(COD) and Total Organic Carbon(TOC).The study can be used for reference of on line wastewater quality measurement.The results are that there are good correlation between the ultraviolet absorption parameters including UV absorption at a UV wavelength of 254 nm(A254) and an integral UV absorption from 226 to 400 nm of UV wavelength ranges(A226,400) and COD or TOC.Then preferable correlation is in A226,400 and TOC,which shows comprehensively the characters of organic contamination in sewage.Futhermore,testing A226,400 was quicker,easier and no consumption of chemical reagent.It was an environmental water-quality analysis technique and can be a substitute for traditional comprehensive index of organic contaminant in sewage to a certain extent.

       

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