碳氮比对生物反硝化中N2O产量的影响

    Effect of ρ(COD)/ρ(N) on Nitrous Oxide(N2O) Production in Biological Denitrification

    • 摘要: 利用间歇式反应器(sequencing batch reactor,SBR),以乙醇作为外加碳源,考察不同化学需氧量(chemicaloxygen demand,COD)与氮的质量浓度的比值对全程和短程反硝化脱氮过程中N2O产量的影响.全程反硝化过程中,调节ρ(COD)/ρ(N)为1.56、2.83、4.56、6.01和10.0,短程反硝化中调节ρ(COD)/ρ(N)为1.51、2.45、3.33、4.13和9.7.结果表明,全程和短程反硝化的最佳ρ(COD)/ρ(N)分别为6.01和4.13,硝酸盐和亚硝酸盐完全被还原,反硝化过程中几乎没有N2O产生,1 g混合液悬浮固体(mixed liquor suspended solids,MLSS)每天还原的硝态氮和亚硝态氮分别可达0.077和0.089 g.在碳源充足的条件下,反硝化速率不再随着有机物的增加而增加.在低ρ(COD)/ρ(N)时,短程反硝化过程中N2O产量远大于全程反硝化过程,最高可达0.607 mg/L.在碳源不足时,亚硝酸盐对氧化亚氮还原酶(N2O reductase,N2OR)的抑制作用和ρ(COD)/ρ(N)不足是影响系统N2O产量增加的主要原因.

       

      Abstract: Sequencing batch reactors (SBR) are used to investigate the greenhouse N2O production in complete and short-cut denitrifications under different ρ(COD)/ρ(N).Using ethanol as carbon source to control ρ(COD)/ρ(N),which are 1.56,2.83,4.56,6.01,and 10.0 in complete denitrification and 1.51,2.45,3.33,4.13,and 9.7 in short-cut denitrification.Results show that 6.01 and 4.13 are the optimum ρ(COD)/ρ(N) in complete and short-cut denitrifications respectively with little N2O production.One gram of mixed liquor suspended solids(MLSS) can reduce 0.077 9 nitrate or 0.089 9 nitrite per day.The specific denitrification rates increase with increasing ρ(COD)/ρ(N).However,there is no remarkable impact with adding organic matter when the carbon source is abundant.When the carbon source is insufficient,N2O production in short-cut denitrification is obviously larger than that in complete denitrification,and the amount topped 0.607 mg/L at ρ(COD)/ρ(N) of 3.33.High N2O production under low ρ(COD)/ρ(N) operations is mainly due to the inhibition of nitrite to the activity of nitrous oxide reductase.

       

    /

    返回文章
    返回