银铂合金纳米流体制备及其热物性影响因素分析

    Analysis of Factors Affecting Thermophysical Properties of Ag-Pt Alloy Nanofluid

    • 摘要: 采用液相还原法,以抗坏血酸(C6 H8 O6)为还原剂,还原六氢氧化铂酸(H2 Pt (OH)6)、醋酸银(CH3 COOAg)制备了水基银铂合金纳米流体。研究流量、温度、表面活性剂(聚乙烯吡络烷酮(PVP))物质的量比等对纳米流体黏度、稳定性、热导率的影响。实验结果表明,在PVP物质的量比为5、流量为0.5 mL/min、反应温度为50℃时,纳米流体的稳定性最好,热导率最高;在流体温度为60℃时,热导率相较于基液增加了16.92%。热导率随PVP物质的量比、反应温度、流量的增加均呈现先增大后减小的趋势。黏度随表面活性剂浓度的增加而增加,随反应温度、流量的增加呈现先减小后增加的趋势。反应温度为50℃时,纳米流体黏度最小,在流体温度为50℃时,相较于去离子水增加了36.51%。

       

      Abstract: In this paper, water-based silver platinum alloy nanofluids were prepared by using ascorbic acid (C6 H8 O6) as reducing agent by reducing platinic acid (H2 Pt (OH)6) and silver acetate (CH3COOAg). The effects of flow rate, temperature and molar ratio of surfactant (PVP) on the viscosity, stability and thermal conductivity of nanofluid were studied. The experimental results show that the stability and thermal conductivity of the nanofluid are the best when the molar ratio of PVP is 5, the flow rate is 0. 5 mL/min and the reaction temperature is 50 ℃. When the fluid temperature is 60 ℃, the thermal conductivity increases by 16. 92% compared with the base fluid. With the increase of PVP molar ratio, reaction temperature and flow rate, the thermal conductivity of nanofluid firstly increased and then decreased. The viscosity of nanofluid increases with the increase of surfactant concentration, and decreases first and then increases with the increase of reaction temperature and flow rate. When the reaction temperature is 50 ℃, the viscosity of the nanofluid is the lowest, and the viscosity of the nanofluid is increased by 36. 51% compared with that of deionized water.

       

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