锂离子电池荷电状态和内部缺陷的超声透射特性仿真研究
Simulation Analysis on Ultrasonic Transmission Characteristics of State of Charge and Internal Defects of Lithium-ion Batteries
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摘要: 采用有限元法分别对锂离子电池的荷电状态、内部缺陷(气泡缺陷、析锂缺陷和浸润不完全缺陷)与超声透射特性之间的影响规律进行了仿真分析。首先,利用Voronoi多边形建立了锂离子电池内部的多层多孔结构;其次,在仿真过程中,通过改变正负极材料的力学参数(杨氏模量和密度)实现了锂离子电池不同荷电状态下超声透射特性的提取。仿真结果表明,随着荷电状态(state of charge,SOC)的增加,快纵波的声强幅值和慢纵波的声强幅值均呈现线性增加的规律,慢纵波的渡越时间呈现线性减小的规律。随后,对锂离子电池内部不同缺陷形式进行仿真分析。通过对比正常电池和缺陷电池的声透射信息可以发现:当锂离子电池底部存在气泡缺陷时,透射信号的声强幅值显著衰减,且随着气泡厚度的增加,声强幅值的衰减也在增加;此外,随着气泡位置的改变,透射信号的声强幅值也呈现规律性变化;当锂离子电池内部存在析锂缺陷时,透射信号的声强幅值和渡越时间均随着析锂厚度的增加而逐渐减小;当锂离子电池内部存在浸润不完全缺陷时,仿真模型将退化为单相多孔介质,频域中也只存在一个频率成分,且声强幅值存在衰减。研究内容解决了用有限元法对锂离子电池荷电状态、内部缺陷进行模拟处理的问题,且慢纵波波速的仿真结果与理论结果吻合良好。Abstract: Using the finite element method, the influence of the state of charge, internal defects (such as bubbles, lithium plating, and unwetted ), and ultrasonic transmission characteristics on lithium-ion batteries is investigated.Firstly, a multi-layer porous structure of the lithium-ion battery was established using Voronoi polygons.Afterwards, the ultrasonic transmission characteristics of the battery under different states of charge (SOC ) were extracted by changing the mechanical parameters (Young's modulus and density) of the anode and cathode.The simulation results indicate a linear increase in the amplitude of fast P-waves and slow P-waves with increasing SOC, as well as a linear decrease in the time of flight of slow P-waves.Secondly, various types of internal defects within the lithium-ion battery were simulated.By comparing the ultrasonic transmission characteristics of normal and defective batteries, it is found that a bubble defect at the bottom of the battery caused a significant attenuation of the transmitted signal's acoustic intensity amplitude, which increased with increasing bubble thickness.The position of the bubble also caused regular changes in the acoustic intensity amplitude of the transmission signal.Lithium plating inside the battery resulted in a gradual decrease in the acoustic intensity amplitude and time of flight of the transmission signal as the thickness of lithium precipitation increased.In the presence of unwetted regions within the battery, the simulation model degrades to a single-phase porous medium with only one frequency component in the frequency domain, leading to attenuation of the acoustic intensity amplitude.This research successfully employs the finite element method to simulate the state of charge and internal defects of lithium-ion batteries.The simulation results of the slow P-wave velocity are in good agreement with the theoretical results.