MOF基材料绿色催化CO2还原研究进展

    Research Progress of CO2 Reduction Catalyzed by MOF-based Materials

    • 摘要: CO2的资源化转化与利用是“双碳”目标达成的重要途径之一.金属-有机框架(metal-organic framework,MOF)因其充足的孔结构、丰富的活性位和可功能化等特性,在CO2催化还原反应中展现出良好的应用前景.总结了基于MOF的新型功能材料依托光、电清洁能源,绿色催化CO2还原的最新研究进展,分别探讨了活性MOF、MOF复合物和MOF衍生物的催化性能,并从理化特性上分析了材料性能优势的成因.在此基础上,对这类新型催化剂面临的主要问题和未来发展做出了总结与展望.

       

      Abstract: Transformation of CO2 into valued-added products is an indispensable part of accomplishing carbon neutrality. Metal-organic frameworks (MOFs) are believed to be promising catalysts for the utilization of CO2, attributing to their well-defined porous structure, abundant active sites and vastly high tunability. The latest researches of MOF-based functional materials as photo- and electro-catalysts for the reduction of CO2 were summarized in this paper. Novel catalysts were divided into three categories, active MOF, MOF composites and MOF derivatives to facilitate the discussion of enhanced activity. The reason of improvement was ascribed to their well-designed physicochemical properties, especially the property of metal sites, coordination situation and morphology of materials. The future progress of research of MOF-based CO2 reduction catalysts was hence proposed.

       

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