氢泄漏光学检测技术综述

    Overview of Optical Detection Technology for Hydrogen Leakage

    • 摘要: 国际上把能源技术革命作为降低碳排放的主要途径,全球很多国家已经或正在制定碳中和计划,氢能具有来源多样、能量密度高、终端零排、用途广泛等多重优势,在保障国家能源安全、改善大气环境质量、推进能源产业升级等方面具有重要意义.综述了用于氢气泄漏检测的光学传感技术,包括可调谐半导体激光吸收光谱技术和钯基光纤传感技术.可调谐吸收光谱技术中介绍了半导体激光波长扫描和调制、光谱吸收、二次谐波信号获取及气体浓度测量的基本原理;以H2检测技术为例,讨论了环境背景吸收谱的影响、目标气体指纹谱的选择原则及可调谐半导体激光器的选择原则;给出了自己研制的智能型可调谐半导体激光吸收光谱气体浓度检测仪的样机结构、模块单元、测试过程和测试结果.钯基光纤传感技术中简述了金属Pd的对H2的传感机理和传感材料的热力学特性;介绍了各种位相调制型、强度调制型和波长调制型光纤传感器的结构、测量原理、测量结果及性能参数;讨论了各类钯基光纤传感器的发展过程;简单分析了传感器宏观性能与微观机理的关系.光学检测属非接触检测,符合氢检测的安全性要求,同时具有选择性强、灵敏度高、响应速度快等特点.

       

      Abstract: The international energy technology revolution is considered as the main way of reducing carbon emissions, and most countries in the world have been or are formulating carbon neutral plan. Hydrogen energy has multiple advantages, such as source variety, high energy density, terminal zero row, and wide range of use. It is of great significance in protecting national energy security, improving the atmospheric environment quality, and promoting energy industrial upgrading. This paper reviewed optical sensing technologies for hydrogen leak detection, including tunable semiconductor laser absorption spectroscopy technology and palladium-based optical fiber sensing technology. Tunable absorption spectroscopy technology introduced the basic principles of semiconductor laser wavelength scanning and modulation, spectral absorption, second harmonic signal acquisition and gas concentration measurement; taking the latest hydrogen detection technology as an example, discussed the impact of environmental background absorption spectra, the selection principle of target gas fingerprint spectrum and the selection principle of tunable semiconductor laser; and obtained the prototype structure, module unit, test process and test result of the intelligent tunable semiconductor laser absorption spectrum gas concentration detector developed by ourselves. Palladium-based optical fiber sensing technology briefly described the sensing mechanism of metal palladium to hydrogen and the thermodynamic properties of sensing materials; introduced the structure, measurement principle, and measurement principle of various phase modulation, intensity modulation and wavelength modulation optical fiber sensors; discussed the development process of various palladium-based optical fiber sensors; and briefly analyzed the relationship between the sensor's macroscopic performance and microscopic mechanism. Optical detection is non-contact, in line with the safety requirements of hydrogen detection, and has the characteristics of strong selectivity, high sensitivity, and fast response speed.

       

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