有氧条件下CO选择性催化还原NOx的研究进展

    Research Progress of CO Selective Catalytic Reduction of NOx Under Oxygen Conditions

    • 摘要: 介绍了近年来有氧条件下CO选择性催化还原(CO selective catalytic reduction,CO-SCR)催化剂的研究现状,重点介绍了Ir基、Pd基、Cu基、Co基催化剂的研究进展,分析了载体种类、助剂和活性组分掺杂量等因素对催化剂活性的影响. 简述了H2O和SO2对催化剂活性的影响,并介绍了CO-SCR的反应机理,为提高CO-SCR催化剂抗氧性提供参考. 最后指出,O2在催化剂表面的反应机理、SO2和H2O对催化剂的毒害机理是今后有氧条件下CO-SCR可能的研究方向.

       

      Abstract: The research status of CO selective catalytic reduction (CO-SCR) catalysts under oxygen conditions in recent years was introduced. The research progress of Ir-based, Pd-based, Cu-based and Co-based catalysts was mainly introduced. The influence of type of carrier, doping modification and active component on the catalyst activity was analyzed. The effects of H2O and SO2 on the activity of catalysts were investigated, and the reaction mechanism of CO-SCR was investigated to provide reference for improving the active of CO-SCR catalysts under oxygen condition. Finally, it is pointed out that it is the possible research directions of CO-SCR in the reaction mechanism of O2 and the toxic mechanism of SO2 and H2O on the catalyst under oxygen condition in the future.

       

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