温拌型抗车辙剂改性沥青流变性能

    Rheological Properties of Modified Asphalt With Warm-mixed Anti-rutting Agent

    • 摘要: 传统抗车辙剂主要是一类以聚烯烃类物质为主体的高分子添加剂,但其存在与沥青胶结料相容性不佳的技术问题. 为了探索与沥青相容性好且具有高熔点特性的改性蜡类材料是否具备用于制备温拌型抗车辙剂的潜质,研究中将传统聚烯烃类抗车辙剂与高温蜡按不同比例混合,制备出系列温拌型抗车辙剂. 将4种抗车辙剂分别按照3%、6%和9%的掺加比例加入基质沥青中制备出12种抗车辙剂改性沥青. 对上述改性沥青进行动态剪切流变(dynamic shear rheometer,DSR)温度扫描、频率扫描和多应力蠕变恢复(multiple stress creep recovery,MSCR)等系列流变性能测试,旨在解析高温蜡组分对抗车辙剂熔体流动性影响的同时,筛选出适用于抗车辙剂改性沥青的高温性能评价指标. 研究结果显示,抗车辙剂中高温蜡含量与抗车辙剂的熔体质量流动速率(melt mass-flow rate,MFR)具有线性相关性. 在低于高温蜡熔点的测试温度下,MFR会随高温蜡比例的增加而降低;在高于高温蜡熔点的情况下,MFR会随高温蜡比例的增加而升高. 鉴于高温蜡高熔点的特征,整体上高温蜡成分会有助于抗车辙剂改性沥青高温性能的提升. 温拌型抗车辙剂中高温蜡比例越高,其对沥青高温性能的改善越好. 研究中高温蜡质量分数为30%的温拌型抗车辙剂对沥青高温性能的改善最佳. 综合比较不同流变评价参数,对于以高弹性特征为主体的抗车辙剂改性沥青,车辙因子和不可恢复蠕变柔量Jnr3.2更适合作为其高温性能的评价指标.

       

      Abstract: Traditional anti-rutting agents are a kind of polymer additive with polyolefin as the main component. However, the poor compatibility between anti-rutting agent with asphalt binder is still a technical problem. To explore whether modified wax materials with good compatibility with asphalt and high melting point have the potential to be adopted in the preparation of warm-mixed anti-rutting agent, series of warm-mixed anti-rutting agents were obtained by mixing traditional polyolefin anti-rutting agents with high temperature wax in different proportions. Four kinds of anti-rutting agents were added with the dosage of 3%, 6%, and 9%, respectively, thus twelve modified asphalts were prepared with the above anti-rutting agents. Dynamic shear rheometer (DSR) was employed to perform the temperature sweep tests, frequency sweep tests and multiple stress creep recovery (MSCR) tests on the above asphalts. The aim of the tests was to analyze the influence of high temperature wax on the melt fluidity performance of anti-rutting agent and also identify suitable evaluation index for anti-rutting agent modified asphalt. Result shows that there is a linear correlation between wax content and melt mass-flow rate (MFR). When the temperature is below the melting point of high temperature wax, MFR decreases as the proportion of high-temperature wax increases. When the temperature is higher than the melting point, MFR increases as the proportion increases. In view of the high melting point of wax mass component, the addition of high temperature wax could help to improve the high temperature performance of anti-rutting agent modified asphalts. The higher ratio of wax in warm-mixed anti-rutting agent, the better the high temperature performance of modified asphalts. Warm-mixed anti-rutting agent with 30% wax content has the best improvement on the high temperature performance of modified asphalts in this study.As to the high elastic characteristics of anti-rutting agent modified asphalt, rutting factor and Jnr3.2 are more suitable to be adopted as high temperature performance evaluation indicators among different rheological evaluation parameters.

       

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