MOF基材料光催化CO2还原为C1产物的研究进展

    Research Progress on Photocatalytic CO2 Reduction to C1 Product Over MOF-based Photocatalysts

    • 摘要: 光催化CO2还原技术清洁环保, 被认为是最有希望的解决方案之一。近年来, 金属-有机框架(metal-organic frameworks, MOF)在光催化CO2还原应用中取得了一些研究成果, 同时, 其明确结构也有利于研究光催化过程中的构效关系。系统总结了MOF基催化剂在光催化CO2还原为C1产物方面的最新研究进展, 重点阐述了MOF基光催化剂制备策略, 其中包括缺陷工程、形态学控制、配体和取代基功能化、掺杂和引入助催化剂、金属簇/纳米粒子修饰、异质结设计与带隙工程和封装量子点等, 以及探讨了MOF基光催化剂在光催化CO2还原反应中的构效关系。最后, 对MOF基光催化CO2还原研究方向进行了展望。

       

      Abstract: In recent years, metal-organic frameworks (MOF) have fascinated remarkable research results in photocatalytic CO2 reduction. The synergistic effect provided by the adjustment of the compositions and structures of MOF has made them ideal candidates for designing versatile photocatalysts with superior performance. In this review, the recent progress in the photocatalytic CO2 reduction to C1 products of MOF-based photocatalysts were summarized. Moreover, different synthesis strategies of MOF-based photocatalysts were mainly discussed, such as defect engineering, morphology control, ligand and substituent functionalization, doping and introducing co-catalysts, metal cluster/nanoparticle modification, heterojunction designing and bandgap engineering as well as encapsulated quantum dots. Finally, the critical challenges and outlook of the MOF-based photocatalysts were proposed.

       

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